Oh. Here's some stuff to think about:
-According to Sheldon Brown, Nexus hubs require a dished cog. The smallest dished 3-tab cogs are 16t. Apparently, a flat cog will rub the hub body or something. I've never tried it myself; I'm a confirmed Sturmey-Archer guy.
-According to Shimano, the lowest direct-drive ratio that is safe to run with Nexus is 2:1, which would be 32x16, 34x17, or 36x18, et cetera...
-Ppl have successfully run lower ratios than that on Nexus.... Others have tried it, and turned their hub's insides into guacamole.
-If you run a 25x16, you might blow your hub up, and your top gear will only be 55". (You'll have a 30" low and a 40" middle gear.) Then again, you might love it.