Well to make more than one, you need to make a mold. But a mold should come from a finished piece. I don't see how you "finish" one in foam. You could make a wood tank, or use a steel tank to make a mold from. Starting with foam and building fiberglass on it is more what you would do for a one off item.
As was stated earlier, there are different resins. The epoxy resin is more expensive and not something you will find in an auto parts store though, just want to point that out. But different foams as was pointed out too.
If you see your self selling fiberglass tanks, I think I would spend my time crafting one from wood. That way you can get all the details you want into the tank, then make a mold from it. A second option for media, would be clay. But again you make a finished looking "model" ( not a prototype as this will not actually work like a tank does ) that will look like a real tank, with all details etc.
What do you think? Which way do you want to go?