As a rule I try to use my best chains for my bikes, BUT
I keep all/most of the (crusty) chains i remove in two medium sized plastic bags, speedy and the kind i usually use, the bags live in a plastic tub. decent and better chains have their own home(s in individual plastic bags with penetrant or lubricant) Then all the bags live in the tub
i squirt penetrating schpritz in the bag(s), wd-40 pb blaster, 3 in one, NBD, every time i disassemble a bike. And every time i put more chains in there - more schpritz, then back on the shelf, i have no idea how many or how long some have been in there
Usually i can find an ok chain in there, sometime i spray again and hit the chain with a plastic scrub brush i keep in one of the bags. But seriously, I try to use the best chains i have available
I always lube the chain(s) at installation because the penetrant usually evaporates quickly, I find they work great as penetrant and crud looseners, but less good as lubricants long term
I have been using silicone as a lubricant , it seems to collect less dirt in my opinion